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1126-09-6 - Ethyl isonipecotate, 98% - Ethyl piperidine-4-carboxylate - H-DL-Inp-OEt - B20601 - Alfa Aesar

B20601 Ethyl isonipecotate, 98%

CAS 번호
1126-09-6
동의어
Ethyl piperidine-4-carboxylate
H-DL-Inp-OEt

사이즈 가격 ($) 수량 재고 여부
25g 38.70
100g 102.00
장바구니에 추가 대량 견적에 추가 항목 보기

Ethyl isonipecotate, 98%

MDL
MFCD00006003
EINECS
214-416-7

화학적 특성

화학식
C8H15NO2
화학 식량
157.21
비등점
203-205°
인화점
80°(176°F)
밀도
1.021
굴절률
1.4600
용해도
Fully miscible with water.

용도

It is used as a reactant for synthesis of SMN protein modulators, β-aryl and β-amino-substituted aliphatic esters by rhodium catalyzed tandem double bond migration/conjugate addition, nitroethylenediamines by nucleophilic ring opening of nitroimidazolidinone. It is also involved in the reactions of RhoA inhibitors for cardiovascular disease therapy and saccharin derived Mannich bases as antimicrobials and antioxidants. It is employed as a reactant for one-pot reductive amination and Suzuki-Miyaura cross coupling of formyl aryl and heteroaryl MIDA boronates.

참고

Store at room temperature. Incompatible with strong oxidizing agents.

참조 문헌

Samantha J. Barry.; Richard M. Carr.; Stephen J. Lane.; William J. Leavens.; Soraya Monté.; Ian Waterhouse. Derivatisation for liquid chromatography/electrospray mass spectrometry: synthesis of pyridinium compounds and their amine and carboxylic acid derivatives.rapid communications in mass spectroscopy. 2003 , 17 (6),603-620 .

Stephen A. Kolodziej.; Susan L. Hockerman.; Gary A. DeCrescenzo.; Joseph J. McDonald.; Debbie A. Mischke.; Grace E. Munie.; Theresa R. Fletcher.; Nathan Stehle.; Craig Swearingen.; Daniel P. Becker. MMP-13 selective isonipecotamide α-sulfone hydroxamates.Bioorg. Med. Chem. Lett. 2010, 20 (12),3561-3564 .

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P210u-P261-P280a-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
118419
통합 관세 코드
2933.39
TSCA(독성물질규제법)"
No

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