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2-Ethylcyclohexanone is used as a pharmaceutical intermediate. 2-Methyl and 2-ethyl derivatives of cyclohexanone were allowed to react with deuterium in tBuOD using platinum group metals as catalysts to study the substituent effects in heterogeneous catalysis.
Shousuke Teratani, Kazunori Tanaka.; Haruo Ogawa.; Kazuo Taya. Substituent effects in heterogeneous catalysis: VIII. Reactions of 2-methyl- and 2-ethylcyclohexanone with deuterium catalyzed by platinum metals. J. Catal. 1981, 70 (2),347-355 .
Herbert C. Brown.; Milorad M. Rogic.; Michael W. Rathke. Reaction of organoboranes with .alpha.-bromo ketones under the influence of potassium tert-butoxide in tetrahydrofuran. A new technique for the .alpha.-alkylation of ketones.J. Am. Chem. Soc. 1968, 90 (22),6218-6219 .