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119-65-3 - Isoquinoline, 97% - B21279 - Alfa Aesar

B21279 Isoquinoline, 97%

CAS 번호
119-65-3
동의어

사이즈 가격 ($) 수량 재고 여부
100g 58.10
500g 186.00
2500g 591.00
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Isoquinoline, 97%

MDL
MFCD00006898
EINECS
204-341-8

화학적 특성

화학식
C9H7N
화학 식량
129.16
융점
24-27°
비등점
241-243°
인화점
107°(225°F)
밀도
1.090
굴절률
1.6245
용해도
Soluble in water (5g/L).

용도

Isoquinoline is used in the manufacture of dyes, paints, antifungal. It is also used as a solvent for the extraction of resins and terpenes.

참고

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

참조 문헌

Maria Chrzanowska.; Maria D. Rozwadowska. Asymmetric Synthesis of Isoquinoline Alkaloids. Chem. Rev. 2004, 104, (7), 3341-3370.

Ryoji. Noyori.; Masako. Ohta.; Yi. Hsiao.; Masato. Kitamura.; Tetsuo. Ohta.; Hidemasa. Takaya. Asymmetric synthesis of isoquinoline alkaloids by homogeneous catalysis. J. Am. Chem. Soc. 1986, 108, (22), 7117-7119.

Reacts with various acid halides in the presence of CN- to give "Reissert compounds" (1-cyano-2-acyl 1,2-dihydro derivatives). For reviews, see: Chem. Rev., 55, 511 (1955); Adv. Het. Chem., 9, 1 (1968); 24, 187 (1979). 1-Alkylisoquinolines can be prepared by alkylation of the Li or Na derivatives of Reissert compounds: Org. Synth. Coll., 4, 641 (1963); 6, 115 (1988). For formation of Reissert compounds from a variety of carbonyl, sulfonyl and phosphoryl halides under milder, phase-transfer conditions, see: Synthesis, 497 (1977). For 'direct' cyanation by a modified Reissert procedure in the presence of tosyl chloride followed by DBU, see: J. Org. Chem., 49, 4056 (1984).

A one-step synthesis of 1-nitroisoquinoline has been reported in which isoquinoline reacts with KNO2 in the presence of acetic anhydride and DMSO. The reaction is considered to be analogous to the Pfitzner-Moffatt oxidation (see Dimethyl­ sulfoxide, A13280): J. Chem. Soc., Perkin 1, 1777 (1996).

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H302-H311-H315-H319

Harmful if swallowed. Toxic in contact with skin. Causes skin irritation. Causes serious eye irritation.

주의 설명서: P280-P305+P351+P338-P301+P312a-P321-P405-P501a

Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Specific treatment (see label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,5222
바일슈타인
107549
위험 등급
6.1
포장 그룹
II
통합 관세 코드
2933.49
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
NW6825000

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