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20717-86-6 - Chlorotitanium triisopropoxide, 95% - Chlorotriisopropoxytitanium - Titanium chloride triisopropoxide - B21914 - Alfa Aesar

B21914 Chlorotitanium triisopropoxide, 95%

CAS 번호
20717-86-6
동의어
Chlorotriisopropoxytitanium
Titanium chloride triisopropoxide

이 품목은 현재 주문할 수 없습니다. 나중에 다시 해 주십시오.

대량 견적에 추가

Chlorotitanium triisopropoxide, 95%

MDL
MFCD00009861

화학적 특성

화학식
C9H21ClO3Ti
화학 식량
260.60
융점
37-44°
비등점
63-66°/0.1mm
인화점
31°(87°F)
밀도
1.091
감도
Moisture Sensitive

참조 문헌

Reacts with the Li enolates of ketones to give Ti(IV) enolates which undergo the aldol condensation with pronounced erythro-selectivity: Tetrahedron Lett., 22, 4691 (1981). This selectivity can be extended to aldehydes by using the Li derivatives of their N,N-dimethylhydrazones: Angew. Chem. Int. Ed., 21, 864 (1982).

/n

In combination with cyclopentylmagnesium bromide, forms a Ti(II) species which mediates the reaction of vinyltributyltin with esters or amides to give trisubstituted cyclopropylstannanes with high diastereoselectivity: J. Org. Chem., 63, 9135 (1998).

/n

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H228-H314-H318

Flammable solid. Causes severe skin burns and eye damage. Causes serious eye damage.

주의 설명서: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

위험 등급
8
포장 그룹
II
통합 관세 코드
2905.19
TSCA(독성물질규제법)"
Yes

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최근에 본 것

화학물질

화학물질

금속 및 재료

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