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98946-18-0 - tert-Butyl 2,2,2-trichloroacetimidate, 97% - 2,2,2-Trichloroacetimidic acid tert-butyl ester - B22039 - Alfa Aesar

B22039 tert-Butyl 2,2,2-trichloroacetimidate, 97%

CAS 번호
98946-18-0
동의어
2,2,2-Trichloroacetimidic acid tert-butyl ester

사이즈 가격 ($) 수량 재고 여부
1g 20.80
5g 55.10
25g 178.00
장바구니에 추가 대량 견적에 추가 항목 보기

tert-Butyl 2,2,2-trichloroacetimidate, 97%

MDL
MFCD00077410
EINECS
000-000-0

화학적 특성

화학식
C6H10Cl3NO
화학 식량
218.51
융점
20-22°
비등점
64-66°/15mm
인화점
55°(131°F)
밀도
1.222
굴절률
1.4570
감도
Moisture Sensitive
용해도
Soluble in organic solvents, cyclo hexane.

용도

tert-Butyl 2,2,2-trichloroacetimidate is used to produce di-tert-butyl peroxide at temperature of -5°C. It may be used in the synthesis of N-α-Fmoc-phospho(1-nitrophenylethyl-2-cyanoethyl)-L-serine, caged building block. It may be used in the conversion of alcohols and carboxylic acids to their respective ethers and esters.

참고

Moisture sensitive. Store away from strong oxidizing agents, heat, water/ moisture.

참조 문헌

Deborah M Rothman; M Eugenio Vazquez; Elizabeth M Vogel; Barbara Imperiali. Caged phospho-amino acid building blocks for solid-phase peptide synthesis. Journal of Organic Chemistry. 2003, 68 (17), 5150-5154.

Gary T. Wang; Sheldon Wang; Robert Gentles; Thomas Sowina; Clarence J. Maring; Dale J. Kempf; Warren M. Kati; Vincent Stoll;, Kent D. Stewart; Design, synthesis, and structural analysis of inhibitors of influenza neuraminidase containing a 2,3-disubstituted tetrahydrofuran-5-carboxylic acid core. Bioorganic & Medicinal Chemistry Letters. 2005, 15 (1-3), 125-128.

Reagent for preparation of t-butyl ethers and esters under mild conditions: J. Chem. Soc., Perkin 1, 2247 (1985); Tetrahedron Lett., 29, 2483 (1988). See also Appendix 6.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
1770049
위험 등급
3
포장 그룹
III
통합 관세 코드
2925.29
TSCA(독성물질규제법)"
No

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