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Allylchlorodimethylsilane is used in the synthesis of cyclo-1,1?,4,4?-bis(1,1,3,3-tetramethyl-1,3-disiloxanediyl)dibenzene, silylating agent for steroids for analysis by GC-MS. Also used in the preparation of phenylenebis(silanediyl triflates), useful synthons for organosilicon polymers, O-silylation of phenyl sulfones.
K. A. Abboud; D. W. Smith Jnr and K. B. Wagener. 3Structure of cyclo-1,1',4,4'-bis(1,1,3,3-tetramethyl-1,3-disiloxanediyl)dibenzene. Acta Cryst.. 1993, 53 (49), 1845-1848.
Yoshimoto Abe; Takahiro Gunji. Oligo- and polysiloxanes. Progress in Polymer Science. 2004, 29 (3), 149-182.
Reagent for the derivatization of steroids for GC-MS: J. Chromat., 129, 384 (1976); J. Chromat. Sci., 17, 115 (1979). See Appendix 4.
해저드 설명서 (EU): H225-H314-H318
Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.
주의 설명서: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.