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16419-60-6 - 2-Methylbenzeneboronic acid, 98% - 2-Methylphenylboronic acid - o-Tolylboronic acid - B23154 - Alfa Aesar

B23154 2-Methylbenzeneboronic acid, 98%

CAS 번호
16419-60-6
동의어
2-Methylphenylboronic acid
o-Tolylboronic acid

사이즈 가격 ($) 수량 재고 여부
1g 38.20
5g 98.00
25g 310.00
장바구니에 추가 대량 견적에 추가 항목 보기

2-Methylbenzeneboronic acid, 98%

MDL
MFCD00093526
EINECS
000-000-0

화학적 특성

화학식
C7H9BO2
화학 식량
135.96
융점
ca 162-164°
용해도
Slightly soluble in water.

용도

2-Methylbenzeneboronic acid is a reagent used for Pd-catalyzed arylation using Suzuki-Miyaura cross-coupling in water, Ruthenium catalyzed direct arylation reactions, Ligand-free copper-catalyzed coupling reactions, Rhodium-catalyzed asymmetric 1,4-addition reactions. Reagent used in Preparation of chiral monophosphorus ligands in asymmetric Suzuki-Miyaura coupling reaction, Human farnesyl pyrophosphate synthase inhibitors as antitumor agents for multiple myeloma cells

참고

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agent.

참조 문헌

Navid Dastbaravardeh; Michael Schnürch; Marko D Mihovilovic. Ruthenium(0)-catalyzed sp3 C-H bond arylation of benzylic amines using arylboronates. Organic Letters. 2012, 14 (7), 1930-1933.

Isidro Cobo; M Isabel Matheu; Sergio Castillón; Omar Boutureira; Benjamin G Davis. Phosphine-free Suzuki-Miyaura cross-coupling in aqueous media enables access to 2-C-aryl-glycosides. Organic Letters. 2012, 14 (7), 1728-1731.

Conditions for ligand-free Suzuki cross-coupling of arylboronic acids with aryl iodides, catalyzed by Palladium(II)­ acetate, 10516, to give unsymmetrical biphenyls in high yield, are described: Org. Synth., 75, 61 (1997). See Appendix 5.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
2935796
통합 관세 코드
2931.90
TSCA(독성물질규제법)"
No
RTECS(화학물질 독성 등록)
ED7777777

권장

최근에 본 것

화학물질

화학물질

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