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937-63-3 - p-Tolyl chlorothionoformate, 97% - B23501 - Alfa Aesar

B23501 p-Tolyl chlorothionoformate, 97%

CAS 번호
937-63-3
동의어

사이즈 가격 ($) 수량 재고 여부
10g 65.60
50g 252.00
장바구니에 추가 대량 견적에 추가 항목 보기

p-Tolyl chlorothionoformate, 97%

MDL
MFCD00014466
EINECS
213-333-3

화학적 특성

화학식
C8H7ClOS
화학 식량
186.66
비등점
70-72°/1mm
인화점
96°(204°F)
밀도
1.210
굴절률
1.5740
감도
Moisture Sensitive
용해도
Miscible with common organic solvents.

용도

p-Tolyl chlorothionoformate is used in dehydration reactions by cyclic elimination of thiocarbonate esters. It acts as a catalyst in the synthesis of alfa-L-2'-deoxythreofuranosyl nucleoside analogs and alkenes from hindered alcohols.

참고

Store in cool place. Incompatible with strong oxidizing agents.

참조 문헌

For examples of the use of aryl chlorothionoformates in dehydration reactions by cyclic elimination of thiocarbonate esters, see Phenyl­ chlorothionoformate, L00838.

Toti, K. S.; Derudas, M.; McGuigan, C.; Balzarini, J.; Van Calenbergh, S. Synthesis and antiviral evaluation of alpha-l-2'-deoxythreofuranosyl nucleosides. Eur. J. Med. Chem. 2011, 46 (9), 3704-3713.

Varaprasad, C. V.; Ramasamy, K. S.; Hong, Z. Synthesis of some monocyclic-N-acetyl 4'-aza-D-nucleosides. J. Heterocycl. Chem. 2006, 43 (2), 325-336.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

주의 설명서: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
1448986
위험 등급
8
포장 그룹
II
통합 관세 코드
2930.90
TSCA(독성물질규제법)"
No

권장

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    Di-n-butyltin dichloride, 96%

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