Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

22037-28-1 - 3-Bromofuran, 97%, stab. with 0.5% calcium carbonate - B23543 - Alfa Aesar

B23543 3-Bromofuran, 97%, stab. with 0.5% calcium carbonate

CAS 번호
22037-28-1
동의어

사이즈 가격 ($) 수량 재고 여부
1g 46.80
5g 148.00
25g 577.00
장바구니에 추가 대량 견적에 추가 항목 보기

3-Bromofuran, 97%, stab. with 0.5% calcium carbonate

MDL
MFCD00005347
EINECS
244-744-6

화학적 특성

화학식
C4H3BrO
화학 식량
146.98
비등점
102-104°
인화점
3°(37°F)
밀도
1.635
굴절률
1.4960
용해도
Soluble in chloroform, ethyl acetate. Insoluble in water.

용도

3-Bromofuran was a synthesis reagent used in the preparation of 2-substituted 3-furfurals. It was also used in the synthesis of 5,6-dehydronorcantharidins. It is one of the volatile metabolites discussed in studies for detecting and discriminating diseases of onion.

참고

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from heat, oxidizing agents.

참조 문헌

Ann Rowley Kelly; Michael H Kerrigan; Patrick J Walsh. Addition/oxidative rearrangement of 3-furfurals and 3-furyl imines: new approaches to substituted furans and pyrroles. Journal of the American Chemical Society. 2008, 130 (12), 4097-4104.

Adam Mc Cluskey; Stephen P Ackland; Michael C Bowyer; Monique L Baldwin; James Garner; Cecilia C Walkom; Jennette A Sakoff. Cantharidin analogues: synthesis and evaluation of growth inhibition in a panel of selected tumour cell lines. Bioorganic Chemistry. 2003, 31 (1), 68-79.

Precursor of 3-lithiofuran by treatment with n-BuLi at low temperatures. Isomerization to 2-lithiofuran tends to occur above -40o: Tetrahedron, 46, 1199 (1990). With LDA at -78o, selective 2-lithiation can be achieved to give 3-bromo-2-lithiofuran, which has been used in synthesis of phenethylthiazolylthiourea (PETT) analogues as potential HIV-1 reverse transcriptase inhibitors: J. Med. Chem., 39, 4261 (1996).

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H225-H315-H319-H335

Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
105337
위험 등급
3
포장 그룹
II
통합 관세 코드
2932.19
TSCA(독성물질규제법)"
No

권장

최근에 본 것

화학물질

화학물질

금속 및 재료

촉매

분석 기기 및 실험실 용품