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623-71-2 - Ethyl 3-chloropropionate, 98% - 3-Chloropropionic acid ethyl ester - B23907 - Alfa Aesar

B23907 Ethyl 3-chloropropionate, 98%

CAS 번호
623-71-2
동의어
3-Chloropropionic acid ethyl ester

이 품목은 현재 주문할 수 없습니다. 나중에 다시 해 주십시오.

대량 견적에 추가

Ethyl 3-chloropropionate, 98%

MDL
MFCD00000989
EINECS
210-809-2

화학적 특성

화학식
ClCH2CH2CO2CH2CH3
화학 식량
136.58
비등점
162-164°
인화점
61°(142°F)
밀도
1.101
굴절률
1.4250
용해도
Immiscible in water.

용도

It can be used to produce (1-ethoxycyclopropyloxy)trimethylsilane by heating.

참고

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

참조 문헌

O. L. Epstein, et al. On the mechanism of titanium-catalyzed cyclopropanation of esters with aliphatic organomagnesium compounds. Deuterium distribution in the reaction products of (CD3)2CHMgBr with ethyl 3-chloropropionate in the presence of titanium tetraisopropoxide.Russ. Chem. Bull.,2000,49(2), 378-380.

Herbert C. Brown, et al. Improved procedure for the asymmetric reduction of prochiral ketones by B-3-pinanyl-9-borabicyclo[3.3.1]nonane.J. Org. Chem.,1982,47(8), 1606-1608.

Reductive cyclization with Na metal in the presence of TMS chloride gives a cyclopropanone acetal, which has been used as a precursor of 1-lithio-1-ethoxycyclopropane: Tetrahedron Lett., 25, 5851 (1984); Org. Synth. Coll., 7, 131 (1990):

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P210u-P261-P280a-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
385698
통합 관세 코드
2915.90
TSCA(독성물질규제법)"
Yes

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