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86-52-2 - 1-(Chloromethyl)naphthalene, 94% - 1-Naphthylmethyl chloride - B24385 - Alfa Aesar

B24385 1-(Chloromethyl)naphthalene, 94%

CAS 번호
86-52-2
동의어
1-Naphthylmethyl chloride

이 품목은 현재 주문할 수 없습니다. 나중에 다시 해 주십시오.

대량 견적에 추가

1-(Chloromethyl)naphthalene, 94%

MDL
MFCD00004042
EINECS
201-678-2

화학적 특성

화학식
C11H9Cl
화학 식량
176.65
융점
31-33°
비등점
291-292°
인화점
132°(270°F)
밀도
1.181
굴절률
1.6370
용해도
Insoluble in water.

용도

1-(Chloromethyl)naphthalene is a key material for synthesis dye pigment and as fluorescent brightening agent. It is employed in synthetic resin and medicine. Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives produce ortho- or para-substituted carbocycles in satisfactory to excellent yields.

참고

Store at room temperature. Incompatible with oxidizing agents and bases.

참조 문헌

Bo Peng.; Sheng Zhang.; Xiaoqiang Yu.; Xiujuan Feng.; Ming Bao. Nucleophilic Dearomatization of Chloromethyl Naphthalene Derivatives via η3-Benzylpalladium Intermediates: A New Strategy for Catalytic Dearomatization. Org. Lett. 2011, 13 (19), 5402-5405 .

Rajendra P. Singh.; Jean'ne M. Shreeve. Recent Highlights in Electrophilic Fluorination with 1-Chloromethyl-4-fluoro- 1,4-diazoniabicyclo[2.2.2]octane Bis(tetrafluoroborate). Acc. Chem. Res. 2004, 37 (1),31-44 .

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H302-H312-H314-H318

Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage.

주의 설명서: P280-P305+P351+P338-P309-P310a

Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER/doctor

기타 참조

바일슈타인
636885
위험 등급
8
포장 그룹
II
통합 관세 코드
2903.99
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
QJ2800000

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