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146374-27-8 - (±)-2-Methyl-2-propanesulfinamide, 97% - (+/-)-tert-Butyl sulfinamide - B25385 - Alfa Aesar

B25385 (±)-2-Methyl-2-propanesulfinamide, 97%

CAS 번호
146374-27-8
동의어
(+/-)-tert-Butyl sulfinamide

사이즈 가격 ($) 수량 재고 여부
1g 47.80
5g 169.00
장바구니에 추가 대량 견적에 추가 항목 보기

(±)-2-Methyl-2-propanesulfinamide, 97%

MDL
MFCD05861480

화학적 특성

화학식
(CH3)3CS(O)NH2
화학 식량
121.20
융점
97-101°
용해도
Soluble in methanol.

용도

(±)-2-Methyl-2-propanesulfinamide is used in the synthesis of 4-sulfonyliminopiperidine and its reaction with benzyl Grignard to form an important pharmaceutical building block, 4-benzyl-4-aminopiperidne. It is also used to prepare spiro tosylaziridines via methylene insertion into the derived sulfonylimine.

참고

Stable under recommended storage conditions. Incompatible with oxidizing agents.

참조 문헌

John J.Caldwell; Ian Collins. Rapid synthesis of 4-benzyl-4-aminopiperidines by addition of Grignard reagents to N-(1-boc-piperidin-4-ylidene)-tert-butanesulfinyl imine. Synlett. 2006, (16), 2565-2568.

 

Joanne Hannam; Timothy Harrison; Felicity Heath; Andrew Madin; Kevin Merchant. Rapid and selective synthesis of substituted 1,2,5-thiadiazolidine 1,1-dioxides. Synlett. 2006, (6), 833-836.

기타 참조

통합 관세 코드
2930.90
TSCA(독성물질규제법)"
No

권장

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