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18741-85-0 - (R)-(+)-1,1'-Bi(2-naphthylamine), 97% - (R)-BINAM - (R)-(+)-2,2'-Diamino-1,1'-binaphthyl - H25785 - Alfa Aesar

H25785 (R)-(+)-1,1'-Bi(2-naphthylamine), 97%

CAS 번호
18741-85-0
동의어
(R)-BINAM
(R)-(+)-2,2'-Diamino-1,1'-binaphthyl

사이즈 가격 ($) 수량 재고 여부
250mg 57.20
1g 158.00
장바구니에 추가 대량 견적에 추가 항목 보기

(R)-(+)-1,1'-Bi(2-naphthylamine), 97%

MDL
MFCD00145204

화학적 특성

화학식
C20H16N2
화학 식량
284.36
융점
242-243°
용해도
Slightly soluble in water.

용도

(R)-(+)-1,1'-Bi(2-naphthylamine) derivatives have been used for asymmetric hydrogenations, cyclopropanations and formation of chiral lactones. It can be used for the synthesis of sterically hindered binaphthalene-based monophosphane ligands.

참고

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible material is strong oxidizing agents.

참조 문헌

Kurt Mislow; Paul Grasemann. Notes - Absolute Configuration of 1,1'-Bi-2-naphthylamine. J. Org. Chem. 1958, 23 (12), 2027-2028.

Shane G. Telfer; Tomohiro Sato; Takunori Harada; Reiko Kuroda; Julie Lefebvre and Daniel B. Leznoff. Mono- and Dinuclear Complexes of Chiral Tri- and Tetradentate Schiff-Base Ligands Derived from 1,1‘-Binaphthyl-2,2‘-diamine. Inorg. Chem. 2004, 43 (20), 6168-6176.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
5279621
통합 관세 코드
2921.59
TSCA(독성물질규제법)"
No

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