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1019-71-2 - Chlorodi(p-tolyl)phosphine, 95% - Di(p-tolyl)chlorophosphine - Chlorobis(4-methylphenyl)phosphine - H25889 - Alfa Aesar

H25889 Chlorodi(p-tolyl)phosphine, 95%

CAS 번호
1019-71-2
동의어
Di(p-tolyl)chlorophosphine
Chlorobis(4-methylphenyl)phosphine

사이즈 가격 ($) 수량 재고 여부
1g 86.70
5g 303.00
장바구니에 추가 대량 견적에 추가 항목 보기

Chlorodi(p-tolyl)phosphine, 95%

MDL
MFCD01630844
EINECS
000-000-0

화학적 특성

화학식
C14H14ClP
화학 식량
248.69
비등점
180-184°/10mm
밀도
1.159
감도
Air & Moisture Sensitive
용해도
Reacts with water.

용도

Chlorodi(p-tolyl)phosphine is used as a reactant for synthesis of palladium catalysts for C-C bond forming cross-coupling reactions, ligands for nickel(0)-catalyzed isomerization reactions, phosphinosulfonamide nickel complexes for oligomerization reactions. It is a reactant for phosphinylation reactions.

참고

Air and moisture sensitive. Incompatible with oxidizing agents, water/ moisture.

참조 문헌

Chi-Feng Lin; Iwao Ojima. Formal enantioselective total synthesis of schulzeines A-C via Pd-catalyzed intramolecular asymmetric allylic amination. Journal of Organic Chemistry. 2011, 76 (15), 6240-6249.

X. Ren; L. Wang and Y. Li. 1,1'-Bis[bis­(4-meth­oxy­phen­yl)phosphan­yl]ferrocene. Acta Cryst. 2012, 68, 922.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

주의 설명서: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

위험 등급
8
포장 그룹
II
통합 관세 코드
2931.39
TSCA(독성물질규제법)"
No

권장

  • H25883

    Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%, may contain suspended dimethylamine hydrochloride crystals
  • H25885

    Chlorobis(3,5-dimethylphenyl)phosphine, tech. 90%
  • H25887

    Chlorobis(4-methoxyphenyl)phosphine, 98+%
  • H25888

    Chlorobis[4-(trifluoromethyl)phenyl]phosphine, 97%
  • H25890

    Chlorodi(o-tolyl)phosphine, 98%

최근에 본 것

화학물질

화학물질

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