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181257-35-2 - Chlorodi(2-furyl)phosphine, 98+% - Di(2-furyl)chlorophosphine - H25892 - Alfa Aesar

H25892 Chlorodi(2-furyl)phosphine, 98+%

CAS 번호
181257-35-2
동의어
Di(2-furyl)chlorophosphine

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대량 견적에 추가

Chlorodi(2-furyl)phosphine, 98+%

MDL
MFCD01630851

화학적 특성

화학식
C8H6ClO2P
화학 식량
200.56
비등점
102-104°/14mm
굴절률
1.5930
감도
Air & Moisture Sensitive
용해도
Reacts with water.

용도

Chlorodi(2-furyl)phosphine is a reactant in the synthesis 2, 2?-bis (di-2-furylphosphino)-1, 1?-binaphthalene. Chlorodi(2-furyl)phosphine is a reactant that is used in the synthesis of centrostereogenic 1,3-bidentate ferrocenyldiphosphane ligands, Ferrocene-based chiral diphosphine, and phosphine containing amino acids. In addition, Chlorodi(2-furyl)phosphine can be used as a reactant for α-Arylation of aldehydes, stereoselective sigmatropic rearrangement of acyclic allylic phosphinites and hydrophosphination of functionalized alkenes

참고

Air & Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture, bases.

참조 문헌

Frédéric Lirona,; Paul Knochel.Stereoselective [2,3] sigmatropic rearrangement of acyclic allylic phosphinites . Chem. Commun., 2004, 2004, 304-305.

Frédéric Lirona,; Paul Knochel. Stereoselective [2,3] sigmatropic rearrangement of acyclic allylic phosphinites. Chem. Commun., 2004, (3), 304-305.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H261-H314-H318

In contact with water releases flammable gas. Causes severe skin burns and eye damage. Causes serious eye damage.

주의 설명서: P223-P231+P232-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Handle under inert gas. Protect from moisture. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

위험 등급
4.3
포장 그룹
II
통합 관세 코드
2932.19
TSCA(독성물질규제법)"
No

권장

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