Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

263369-88-6 - Chlorobis(2-methoxyphenyl)phosphine, 98+% - Bis(2-methoxyphenyl)chlorophosphine - H25894 - Alfa Aesar

H25894 Chlorobis(2-methoxyphenyl)phosphine, 98+%

CAS 번호
263369-88-6
동의어
Bis(2-methoxyphenyl)chlorophosphine

사이즈 가격 ($) 수량 재고 여부
1g 101.00
5g 307.00
장바구니에 추가 대량 견적에 추가 항목 보기

Chlorobis(2-methoxyphenyl)phosphine, 98+%

MDL
MFCD08064037
EINECS
000-000-0

화학적 특성

화학식
C14H14ClO2P
화학 식량
280.69
융점
111-114°
감도
Air & Moisture Sensitive
용해도
Reacts with water.

용도

Chlorobis(2-methoxyphenyl)phosphine is used as a reactant for cycloadditions reactions, asymmetric hydrogenation and allylic substitution, asymmetric hydrogenation of imines and olefins. It is also used as a reactant for synthesis of ferrocene-based chiral diphosphine, catalysts for C-C cross coupling reactions, palladium complexes.

참고

Air and moisture sensitive. Incompatible with oxidizing agents, bases, water/ moisture.

참조 문헌

Anna Trifonova; Jarle S. Diesen; Pher G. Andersson Prof. Dr. Asymmetric Hydrogenation of Imines and Olefins Using Phosphine-Oxazoline Iridium Complexes as Catalysts. Chemistry - A European Journal. 2006, 12 (8), 2318-2328.

Sandra Brun; Magda Parera; Anna Pla-Quintana; Anna Roglans; Thierry León; Thierry Achard; Jordi Solà; Xavier Verdaguer; Antoni Riera. Chiral N-phosphino sulfinamide ligands in rhodium(I)-catalyzed [2+2+2] cycloaddition reactions. Tetrahedron. 2010, 66 (46), 9032-9040.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

주의 설명서: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

위험 등급
8
포장 그룹
II
통합 관세 코드
2931.39
TSCA(독성물질규제법)"
No

권장

  • H25882

    Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine, 94%
  • H25887

    Chlorobis(4-methoxyphenyl)phosphine, 98+%
  • H25889

    Chlorodi(p-tolyl)phosphine, 95%
  • H25890

    Chlorodi(o-tolyl)phosphine, 98%

최근에 본 것

화학물질

화학물질

금속 및 재료

촉매

분석 기기 및 실험실 용품