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88335-93-7 - (1S,2R)-cis-4-Cyclohexene-1,2-dicarboxylic acid 1-monomethyl ester, 98% - (1S,2R)-1-Methyl cis-1,2,3,6-tetrahydrophthalate - (1S,2R)-1-Methyl cis-4-cyclohexene-1,2-dicarboxylate - H25950 - Alfa Aesar

H25950 (1S,2R)-cis-4-Cyclohexene-1,2-dicarboxylic acid 1-monomethyl ester, 98%

CAS 번호
88335-93-7
동의어
(1S,2R)-1-Methyl cis-1,2,3,6-tetrahydrophthalate
(1S,2R)-1-Methyl cis-4-cyclohexene-1,2-dicarboxylate

사이즈 가격 ($) 수량 재고 여부
1g 95.40
5g 336.00
장바구니에 추가 대량 견적에 추가 항목 보기

(1S,2R)-cis-4-Cyclohexene-1,2-dicarboxylic acid 1-monomethyl ester, 98%

MDL
MFCD00075490
EINECS
000-000-0

화학적 특성

화학식
C9H12O4
화학 식량
184.19
융점
64-67°
용해도
Insoluble in water.

용도

(1S,2R)-cis-4-Cyclohexene-1,2-dicarboxylic acid 1-monomethyl ester is used in organic synthesis as a starting material and intermediate.

참고

Incompatible with strong oxidizing agents, strong acid and bases.

참조 문헌

Goswami, A.; Kissick, T. P. Enzymatic Desymmetrization of Dimethyl Cylcohex-4-ene-cis-1,2-dicarboxylate to (1S,2R)-2-(Methoxycarbonyl)cyclohex-4-ene-1-carboxylic Acid. Org. Process Res. Dev. 2009, 13 (3), 483-488.

Solano, D. M.; Hoyos, P.; Hernáiz, M. J.; Alcántara, A. R.; Sánchez-Montero, J. M. Industrial biotransformations in the synthesis of building blocks leading to enantiopure drugs. Bioresour. Technol. 2012, 115, 196-207.

Su?ss, P.; Illner, S.; von Langermann, J.; Borchert, S.; Bornscheuer, U. T.; Wardenga, R.; Kragl, U. Scale-Up of a Recombinant Pig Liver Esterase-Catalyzed Desymmetrization of Dimethyl Cyclohex-4-ene-cis-1,2-dicarboxylate. Org. Process Res. Dev. 2014, 18 (7), 897-903.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
5262096
통합 관세 코드
2917.20
TSCA(독성물질규제법)"
No

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