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4334-88-7 - 4-(Ethoxycarbonyl)benzeneboronic acid, 94% - 4-Ethoxycarbonylphenylboronic acid - Ethyl 4-boronobenzoate - H26356 - Alfa Aesar

H26356 4-(Ethoxycarbonyl)benzeneboronic acid, 94%

CAS 번호
4334-88-7
동의어
4-Ethoxycarbonylphenylboronic acid
Ethyl 4-boronobenzoate

사이즈 가격 ($) 수량 재고 여부
1g 66.70
5g 203.00
장바구니에 추가 대량 견적에 추가 항목 보기

4-(Ethoxycarbonyl)benzeneboronic acid, 94%

MDL
MFCD02179441

화학적 특성

화학식
C9H11BO4
화학 식량
193.99
융점
137-140°

용도

4-(Ethoxycarbonyl)benzeneboronic acid is used as a reactant involved in oxidative hydroxylation for the preparation of phenols, homolytic aromatic substitution, cross-coupling with α-bromocarbonyl compounds, Suzuki-coupling reaction with quinoline carboxylates, trifluoromethylation and carbometalation of ynamides.

참고

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

참조 문헌

Nanase Uchiyama.; Eiji Shirakawa.; Ryo Nishikawa.; Tamio Hayashi. Iron-catalyzed oxidative coupling of arylboronic acids with benzene derivatives through homolytic aromatic substitution. Chemical Communications. 2011, 47 (42), 11671-11673.

Kiyofumi Inamoto.; Kanako Nozawa.; Misato Yonemoto.; Yoshinori Kondo. Micellar system in copper-catalyzed hydroxylation of arylboronic acids: facile access to phenols. Chemical Communications. 2011, 47 (42), 11775-11777.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

통합 관세 코드
2931.90
TSCA(독성물질규제법)"
No

권장

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