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193065-68-8 - 2-(Ethoxycarbonyl)ethylzinc bromide, 0.5M in THF - 3-Ethoxy-3-oxopropylzinc bromide - H26739 - Alfa Aesar

H26739 2-(Ethoxycarbonyl)ethylzinc bromide, 0.5M in THF

CAS 번호
193065-68-8
동의어
3-Ethoxy-3-oxopropylzinc bromide

사이즈 가격 ($) 수량 재고 여부
50ml 137.00
장바구니에 추가 대량 견적에 추가 항목 보기

2-(Ethoxycarbonyl)ethylzinc bromide, 0.5M in THF

MDL
MFCD00671976

화학적 특성

화학식
BrZnCH2CH2COOCH2CH3
화학 식량
246.42
인화점
-17°(1°F)
밀도
0.972
용해도
Reacts with water.

용도

In many of the reactions, organozinc compounds appear as intermediates. Some of the synthetic uses of organozinc compounds are: for the stereo selective alkylation reaction of cyclic ketones, conjugate addition reaction to alpha, beta-unsaturated carbonyl compounds, ring opening reactions of epoxides and oxo vanadium-induced ligand coupling of aryltrimethyl zincates.

참고

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, air, water, moisture and heat.

참조 문헌

Knochel, P,; Singer, R. D. “Preparation and Reactions of Polyfunctional Organozinc Reagents in Organic Synthesis. Chem. Rev. 1993, 93 2117-2188 .

Kim, S.-H.; Rieke, R. D. “Recent Advance in Heterocyclic Organozinc and Organomanganese Compounds; Direct Synthetic Routes and Application in Organic Synthesis”.Molecules. 2010, 15 8006-8038..

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H225-H261-H302-H333-H314-H318-H351-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. Harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.

주의 설명서: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

위험 등급
4.3
포장 그룹
II
통합 관세 코드
2931.90
TSCA(독성물질규제법)"
No

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