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30282-14-5 - 2-Hydroxycyclohexanone dimer, 90+% - Adipoin - H27199 - Alfa Aesar

H27199 2-Hydroxycyclohexanone dimer, 90+%

CAS 번호
30282-14-5
동의어
Adipoin

사이즈 가격 ($) 수량 재고 여부
1g 20.20
5g 49.40
25g 129.00
장바구니에 추가 대량 견적에 추가 항목 보기

2-Hydroxycyclohexanone dimer, 90+%

MDL
MFCD00151157

화학적 특성

화학식
C12H20O4
화학 식량
228.28
융점
100-107°
비등점
83-86°/13mm
인화점
79°(174°F)
용해도
Partly miscible in water.

용도

It is a reactant involved in the synthesis of substrates for tin tetrachloride mediated fragmentation to produce ynones and ynoates, tandem oxidation coupling reactions with diamines, asymmetric allylic alkylation of enolates and formate reduction of allylic carbonates for polypropionate systems.

참고

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Keep away from ignition sources. Protect from electrostatic charges. Ensure adequate ventilation.

참조 문헌

Barry M Trost, et al. Enantioselective synthesis of alpha-tertiary hydroxyaldehydes by palladium-catalyzed asymmetric allylic alkylation of enolates.J Am Chem Soc.,2009,129(2), 282-3.

Ali Bayir, et al. Preparation of tethered aldehyde ynoates and ynones by ring fragmentation of cyclic gamma-oxy-beta-hydroxy-alpha-diazo carbonyls.J Org Chem.,2010,75(2), 296-302.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H228-H315-H319-H335

Flammable solid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P210-P280g-P305+P351+P338

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

기타 참조

위험 등급
4.1
포장 그룹
III
통합 관세 코드
2932.99
TSCA(독성물질규제법)"
No

권장

최근에 본 것

화학물질

화학물질

금속 및 재료

촉매

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