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142691-70-1 - 1,1'-Bis(dichlorophosphino)ferrocene, 98% - H27293 - Alfa Aesar

H27293 1,1'-Bis(dichlorophosphino)ferrocene, 98%

CAS 번호
142691-70-1
동의어

사이즈 가격 ($) 수량 재고 여부
250mg 59.10
1g 146.00
장바구니에 추가 대량 견적에 추가 항목 보기

1,1'-Bis(dichlorophosphino)ferrocene, 98%

MDL
MFCD01630854

화학적 특성

화학식
C10H8Cl4FeP2
화학 식량
387.78
감도
Moisture Sensitive
용해도
Reacts with water.

용도

It is applied as a reactant for synthesis of ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation, metallocene-bridged bisphosphaalkene and as a catalyst for synthesis of oligonuclear heterometallic complexes.

참고

Moisture sensitive. Store away from water/moisture, strong bases and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.

참조 문헌

Carmen Moser, et. al. The homologous series of 1,1'-ferrocenylenebisdihalophosphanes (C5H4PX2)2Fe (X = F, Cl, Br, I): precursors for the first metallocene bridged bisphosphaalkene.Dalton Trans.,2006,732(7), 3879-3885.

Xingao Peng, et al. Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation.Tetrahedron Lett.,2008,49(33), 4862-4864.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

주의 설명서: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

위험 등급
8
포장 그룹
II
통합 관세 코드
2931.39
TSCA(독성물질규제법)"
No

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