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H27351 (R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl

CAS 번호
190003-81-7
동의어
(R)-Xylyl-H8-BINAP

이 품목은 현재 주문할 수 없습니다. 나중에 다시 해 주십시오.

대량 견적에 추가

(R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl

MDL
MFCD06796646

화학적 특성

화학식
C52H56P2
화학 식량
742.97
Storage & Sensitivity
Air Sensitive. Ambient temperatures.
용해도
Insoluble in water.

용도

Used in the synthesis of organometallic catalysts. For coupling reactions, addition reactions, asymmetric hydrogenation, asymmetric hydroboration.

참고

Air Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, air.

참조 문헌

Jianrong (Steve) Zhou,; John F. Hartwig. Intermolecular, Catalytic Asymmetric Hydroamination of Bicyclic Alkenes and Dienes in High Yield and Enantioselectivity. J. Am. Chem. Soc. 2008 , 130 (37),12220-12221.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

통합 관세 코드
2931.39
TSCA(독성물질규제법)"
No

권장

  • A10595

    Trimethyl phosphate, 98+%
  • A12099

    2,3-Dibromo-1-propene, tech. 85%, stab. with copper

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