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50816-19-8 - 8-Bromo-1-octanol, 95% - Octamethylene bromohydrin - H27628 - Alfa Aesar

H27628 8-Bromo-1-octanol, 95%

CAS 번호
50816-19-8
동의어
Octamethylene bromohydrin

사이즈 가격 ($) 수량 재고 여부
1g 46.80
5g 148.00
25g 460.00
장바구니에 추가 대량 견적에 추가 항목 보기

8-Bromo-1-octanol, 95%

MDL
MFCD00010388
EINECS
256-785-7

화학적 특성

화학식
C8H17BrO
화학 식량
209.13
비등점
79-80°/0.07mm
인화점
>110°(230°F)
밀도
1.220
굴절률
1.4810

용도

It is used to produce 8-phenylselanyl-octan-1-ol by reaction with diphenyl-diselane. The reaction occurs with reagent sodium borohydride and solvent ethanol at ambient temperature. The yield is about 96%. 8-Bromo-1-octanol was used in the synthesis of (E)-10-hydroxy-2-decenoic acid (royal jelly acid)1. It was also used in the synthesis of (Z)-14-methyl-9-pentadecenoic acid.

참고

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents. Refrigerated (4°C).

참조 문헌

R Chiron. New synthesis of royal jelly acid.. Journal of Chemical Ecology. 1982, 8 (4), 709-713

Carballeira NM,; Sanabria D,;Oyola D. An improved synthesis for the (Z)-14-methyl-9-pentadecenoic acid and its topoisomerase I inhibitory activity. ARKIVOC. 2007, 8 (49-57).

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H315-H319

Causes skin irritation. Causes serious eye irritation.

주의 설명서: P280a-P264-P305+P351+P338-P321-P332+P313-P337+P313

Wear protective gloves and eye/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists:

기타 참조

바일슈타인
1900837
통합 관세 코드
2905.59
TSCA(독성물질규제법)"
Yes

권장

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  • A18862

    2-Dodecanone, 95%
  • B25165

    Trimethylenebis(triphenylphosphonium bromide), 98+%

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