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A double Suzuki cross-coupling protocol has been devised as a practical route to a variety of terphenyls. Good chemoselectivity was observed. Unsymmetrically substituted triphenylenes were also easily prepared. A double Suzuki cross-coupling protocol has been devised as a practical route to a variety of terphenyls and triphenylenes.
M.J. Sharp,; W. Cheng,; V. Snieckus. Synthetic connections to the aromatic directed metalation reaction. Functionalized aryl boronic acids by ipso borodesilylation. General syntheses of unsymmetrical biphenyls and m-terphenyls. Tetrahedron Letters. 1987, 28 (43),5093-5096.
Daniele Simonia,; Giuseppe Gianninib,; Pier Giovanni Baraldia,; Romeo Romagnolia,; Marinella Robertic,; Riccardo Rondanina,; Riccardo Baruchelloa,; Giuseppina Grisoliaa,; Marcello Rossia,; Danilo Mirizzia,; Francesco Paolo Invidiatad,; Stefania Grimaudoe,; Manlio Tolomeo. A convenient synthesis of unsymmetrically substituted terphenyls of biologically active stilbenes via a double Suzuki cross-coupling protocol. Tetrahedron Letters. 2003, 44 (14), 3005-3008.
해저드 설명서 (EU): H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
주의 설명서: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.