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80875-98-5 - (2S,3aS,7aS)-Octahydroindole-2-carboxylic acid, 98% - H27894 - Alfa Aesar

H27894 (2S,3aS,7aS)-Octahydroindole-2-carboxylic acid, 98%

CAS 번호
80875-98-5
동의어

사이즈 가격 ($) 수량 재고 여부
1g 69.10
5g 203.00
장바구니에 추가 대량 견적에 추가 항목 보기

(2S,3aS,7aS)-Octahydroindole-2-carboxylic acid, 98%

MDL
MFCD07782125

화학적 특성

화학식
C9H15NO2
화학 식량
169.22
융점
266° dec.
선광도
-50 (c=1 in methanol)
용해도
Soluble in methanol and water.

용도

An intermediate in the synthesis of Perindopril. The completely diastereoselective α-alkylation of oxazolidinone provides a very convenient and concise route to enantiopure α-tetrasubstituted derivatives of this Oic stereoisomer.

참고

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents. Store at -20°C.

참조 문헌

Francisco J. Sayago,; M. Isabel Calaza,; Ana I. Jiménez,; Carlos Cativiela. A straightforward route to enantiopure α-substituted derivatives of (2S,3aS,7aS)-octahydroindole-2-carboxylic acid. Journal name. 2009, 65(27) ,5174-5180.

Francisco J. Sayago,; M. Isabel Calaza,; Ana I. Jiménez,; Carlos Cativiela. Versatile methodology for the synthesis and α-functionalization of (2R,3aS,7aS)-octahydroindole-2-carboxylic acid. Tetrahedron. 2008, 64(1), 84-91.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

통합 관세 코드
2933.99
TSCA(독성물질규제법)"
No

권장

  • A17629

    Sodium thiosulfate, anhydrous, 99%
  • B25745

    4,16-Dibromo[2.2]paracyclophane, 98%

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