Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

A14390 Neopentyl alcohol, 99%

Número CAS
75-84-3
Sinónimos
2,2-Dimethyl-1-propanol

Stock No. Tamanho Preço ($) Quantidade Disponibilidade
A14390-14 25g 37,60
A14390-22 100g 92,10
A14390-36 500g 385,00
Adicionar ao cesto de compras Adicionar ao orçamento a granel Ver artigo

Neopentyl alcohol, 99%

MDL
MFCD00004682
EINECS
200-907-3

Propriedades químicas

Fórmula
(CH3)3CCH2OH
Peso da fórmula
88.15
Temperatura de fusão
52-56°
Temperatura de ebulição
111-114°
Temperatura de inflamação
36°(96°F)
Densidade
0.818
Storage & Sensitivity
Ambient temperatures.
Solubilidade
Soluble in water at (20°C 40 g/L), alcohol, and ether. Solubility in methanol is almost transparent.

Aplicações

It is used in the Mitsunobu reaction of methyl salicylate coupling of sterically hindered substrates.

Notas

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Referências de literatura

Sudhakar Bhandaru, et al. Synthesis of a C14',15' dihydro derivative of the south hexacyclic steroid unit of cephalostatin 1. Part I : regiospecific Rh[II]-mediated intermolecular oxygen alkylation of a primary neopentyl alcohol.Tetrahedron Lett.,1995,36(46), 8347-8350.

J. D. Slagle, et al. Mechanism of the triphenylphosphine-tetrachloromethane-alcohol reaction: pericyclic or clustered ion pairs?J. Org. Chem.,1981,46(17), 3526-3530.

A method has been described for conversion to the iodide using a combination of methyl iodide and triphenyl phosphite: Org. Synth. Coll., 6, 830 (1988).

Advertências de perigo e prevenção GHS

Advertências de perigo (UE): H228

Flammable solid.

Advertências de prevenção: P210-P280a-P240-P241-P370+P378a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. In case of fire: Use for extinction: CO2, powder or water spray.

Outras referências

Merck
14,6457
Beilstein
1730984
Classe de perigo
4.1
Grupo de embalamento
II
Código de tarifas harmonizado
2905.19
TSCA
Yes

Recomendado

Vistos recentemente

Químicos

Ciências da vida

Metais e materiais

Catalisadores

Equipamento analítico e de laboratório