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It is used in the Mitsunobu reaction of methyl salicylate coupling of sterically hindered substrates.
Sudhakar Bhandaru, et al. Synthesis of a C14',15' dihydro derivative of the south hexacyclic steroid unit of cephalostatin 1. Part I : regiospecific Rh[II]-mediated intermolecular oxygen alkylation of a primary neopentyl alcohol.Tetrahedron Lett.,1995,36(46), 8347-8350.
J. D. Slagle, et al. Mechanism of the triphenylphosphine-tetrachloromethane-alcohol reaction: pericyclic or clustered ion pairs?J. Org. Chem.,1981,46(17), 3526-3530.
A method has been described for conversion to the iodide using a combination of methyl iodide and triphenyl phosphite: Org. Synth. Coll., 6, 830 (1988).
Advertências de perigo (UE): H228
Advertências de prevenção: P210-P280a-P240-P241-P370+P378a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. In case of fire: Use for extinction: CO2, powder or water spray.